118 This substance may not be transported under the provisions of Division 4.1 unless specifically authorized by the Associate Administrator (see UN0143 or UN0150 as appropriate). For continued use of approvals dated prior to January 1, 2012, see 173.308(b)(5). (1) Even though certain packagings are specified in this part, it is, nevertheless, the responsibility of the person offering a hazardous material for transportation to ensure that such packagings are compatible with their lading. The letter codes are placed in front of the number codes (for example, "A29"). US DOT's Hazardous Materials Regulations (HMR) list more than 3,000 shipping names for regulated materialsfrom acetal to zirconium tetrachloride. e. A description to which special provision 170 or TP7 is assigned in Column 7 of the 172.101 Hazardous Materials Table, and therefore requires air to be eliminated from the package vapor space by nitrogen or other means, must not be offered for transportation under this description. Kits that are carried on board transport vehicles for first aid or operating purposes are not subject to the requirements of this subchapter. 1/1.1 TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. Hazardous materials necessary for the safe and proper operation of the cargo transport unit (e.g., fire extinguishing systems and air conditioning systems), must be properly secured to or installed in the cargo transport unit and are not otherwise subject to this subchapter. 387 When materials are stabilized by temperature control, the provisions of 173.21(f) of this subchapter apply. An unused lighter or a lighter that is cleaned of residue and purged of vapors is not subject to the requirements of this subchapter. The packing group assignment and packaging must be approved by the Associate Administrator for Hazardous Materials Safety on the basis of the criteria in 173.21 of this subchapter and the package type used for the Series 6(c) test. B45 Each tank must have a reclosing combination pressure relief device equipped with stainless steel or platinum rupture discs approved by the AAR Tank Car Committee. 440 When this material is transported by tank car, the offeror must ensure each tank car is remotely monitored for pressure and location. The examination and testing of each lighter design must be performed by a person authorized by the Associate Administrator under the provisions of subpart E of part 107 of this chapter, as specified in 173.308(a)(4). 335 Mixtures of solids that are not subject to this subchapter and environmentally hazardous liquids or solids may be classified as Environmentally hazardous substances, solid, n.o.s, UN3077 and may be transported under this entry, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. N73 Packagings consisting of outer wooden or fiberboard boxes with inner glass, metal or other strong containers; metal or fiber drums; kegs or barrels; or strong metal cans are authorized and need not conform to the requirements of part 178 of this subchapter. be marked with the hydrostatic pressure test marking specified in 173.24a(b)(4). After unloading, the residual material also must be covered with an inert gas or the container must be filled with water to the tank's capacity. W100 Non-bulk flexible, fibreboard or wooden packagings must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. 325 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. Furthermore, lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must be described using the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. DOT Specification 57 port-able tanks used for the transport by vessel of Class 3, Packaging Group II materials must conform to the fol-lowing: (1) Minimum design pressure. This training must be documented in training records required by 172.704(d). TP9 A hazardous material assigned to special provision TP9 in Column (7) of the 172.101 Table may only be transported in a portable tank if approved by the Associate Administrator. 16 This description applies to smokeless powder and other solid propellants that are used as powder for small arms and have been classed as Division 1.3C, 1.4C and Division 4.1 in accordance with 173.56 of this subchapter. c. The motor carrier must maintain a satisfactory safety rating as prescribed in 49 CFR part 385. B42 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105J. B10 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks, and DOT 57 portable tanks are not authorized. 5 If this material meets the definition for a material poisonous by inhalation (see 171.8 of this subchapter), a shipping name must be selected which identifies the inhalation hazard, in Division 2.3 or Division 6.1, as appropriate. A20 Plastic bags as inner receptacles of combination packagings are not authorized for transportation by aircraft. B131 When transported by highway, rail, or cargo vessel, waste Paint and Paint related material (UN1263; PG II and PG III), when in plastic or metal inner packagings of not more than 26.5 L (7 gallons), are excepted from the marking requirements in 172.301(a) and (c) and the labeling requirements in 172.400(a), when further packed in the following specification and non-specification bulk outer packagings and under the following conditions: a. (9) A code containing the letter W refers to a special provision that applies only to transportation by water. Interpretation Response Details. 346 Nitrogen, refrigerated liquid (cryogenic liquid), UN1977 transported in accordance with the requirements for open cryogenic receptacles in 173.320 and this special provision are not subject to any other requirements of this subchapter. in such a manner as to prevent short circuits, accidental operation, and significant movement relative to the cargo transport unit under the shocks, loadings, and vibrations normally incident to transport. The lithium batteries must meet the requirements of 173.185(a) and contain the necessary systems to prevent overcharge and over discharge between the batteries. 238 Neutron radiation detectors: Neutron radiation detectors containing non-pressurized boron trifluoride gas in excess of 1 gram (0.035 ounces) and radiation detection systems containing such neutron radiation detectors as components may be transported by highway, rail, vessel, or cargo aircraft in accordance with the following: a. - Other Regulations Relating to Transportation, - Pipeline and Hazardous Materials Safety Administration, Department of Transportation, - Hazardous Materials Table, Special Provisions, Hazardous Materials Communications, Emergency Response Information, Training Requirements, and Security Plans, - Table of Hazardous Materials and Special Provisions, https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-172/subpart-B/section-172.102. c. Self-propelled vehicles or equipment that also contain an internal combustion engine must be described using the entries Engine, internal combustion, flammable gas powered or Engine, internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. N91 The use of a non specification sift-proof, non-bulk, metal can with or without lid, or a non specification sift-proof, non-bulk fiber drum, with or without lid is authorized when transporting coal tar pitch compounds by motor vehicle or rail freight. Single unit tank car tanks must have a reclosing pressure relief device having a start-to-discharge pressure set at no more than 1551 kPa (225 psig). 200 Division 1.4G consumer fireworks may be certified for transportation by a DOT-approved Fireworks Certification Agency in accordance with the provisions of 173.65 of this subchapter. Additionally, self-propelled vehicles or equipment that contain a fuel cell engine must be described using the entries Engine, fuel cell, flammable gas powered or Engine, fuel cell, flammable liquid powered or Vehicle, fuel cell, flammable gas powered or Vehicle, fuel cell, flammable liquid powered, as appropriate. (c)Column 2: Hazardous materials descriptions and proper shipping names. IBCs must have a device to allow venting. 5. 168 For lighters containing a Division 2.1 gas (see 171.8 of this subchapter), representative samples of each new lighter design must be examined and successfully tested as specified in 173.308(b)(3). (7) Special Provisions (172.102) IB8, IP2, IP4 Except for transportation by aircraft, in palletized loads, a pallet box or unit load device (e.g. Wall thickness must be verified ultrasonically at intervals midway between periodic hydraulic tests (every 2.5 years). In addition, for solid materials, special provision B54 applies. Liquefied compressed gases are assigned to portable tank instruction T50. B15 Packagings must be protected with non-metallic linings impervious to the lading or have a suitable corrosion allowance. 145 This entry applies to formulations that neither detonate in the cavitated state nor deflagrate in laboratory testing, show no effect when heated under confinement, exhibit no explosive power, and are thermally stable (self-accelerating decomposition temperature (SADT) at 60 C (140 F) or higher for a 50 kg (110.2 lbs.) You can For Federal Register citations affecting 172.102, see the List of CFR Sections Affected, which appears in the Finding Aids section of the printed volume and at www.govinfo.gov. These batteries are typically used for portable power applications. The only tank car tanks authorized are Class DOT 105 tank cars having a test pressure of 2,069 kPa (300 psig) or greater. See also UN1942 in the 172.101 Hazardous Materials Table. N65 Outage must be sufficient to prevent cylinders or spheres from becoming liquid full at 55 C (130 F). The article, machinery, or apparatus, if unpackaged, or the packaging in which it is contained shall be marked Dangerous goods in articles or Dangerous goods in machinery or Dangerous goods in apparatus as appropriate, with the identification number UN3363. 382 Packages containing toy plastic or paper caps for toy pistols described as UN0349, Articles, explosive, n.o.s. 148 For domestic transportation, this entry directs to 173.66 for: a. [Amdt. (9) W codes. 105 The word Agents may be used instead of Explosives when approved by the Associate Administrator. shipping name in Column (1) of the 172.101 Table, it means that the mate-rial is known to pose a risk to humans. However, the hazard label corresponding to the hazard class or division may be substituted for the marking. They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). A 25 mm (1 inch) woven lining of asbestos or other approved material must be placed between the bolster slabbing and the bottom of the tank. A portable tank may be offered for transport after the date of expiry of the last lining inspection for a period not to exceed three months for purposes of performing the next required test or inspection, after emptying but before cleaning. N89 When steel UN pressure receptacles are used, only those bearing the H mark are authorized. individual packaging placed or stacked and secured by strapping, shrink or stretch-wrapping or other suitable means to a pallet). TP10 A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority, is required. The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage. 146 This description may be used for a material that poses a hazard to the environment but does not meet the definition for a hazardous waste or a hazardous substance, as defined in 171.8 of this subchapter, or any hazard class, as defined in part 173 of this subchapter, if it is designated as environmentally hazardous by another Competent Authority. Hazardous materials shipped under this entry are excepted from the labeling requirements of this subchapter unless offered for transportation or transported by aircraft and are not subject to the placarding requirements of subpart F of this part. (iii) T50 When portable tank instruction T50 is indicated in Column (7) of the 172.101 Hazardous Materials Table, the applicable liquefied compressed gas and chemical under pressure descriptions are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. The consignor shall be in possession of a copy of each applicable certificate when packages include fissile material excepted by competent authority approval. Primary receptacles must be further packed in non-specification bulk outer packagings such as cubic yard boxes, plastic rigid-wall bulk containers, dump trailers, and roll-off containers. Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to the requirements of this subchapter. 379 When offered for transport by highway, rail, or cargo vessel, anhydrous ammonia adsorbed or absorbed on a solid contained in ammonia dispensing systems or receptacles intended to form part of such systems is not subject to the requirements of this subchapter if the following conditions in this provision are met. N85 Packagings certified at the Packing Group I performance level may not be used. Please do not provide confidential B80 Each cargo tank must have a minimum design pressure of 276 kPa (40 psig). No more than four bottles, securely closed with threaded caps, may be packed in each box. If a vehicle is powered by a flammable liquid and a flammable gas internal combustion engine, it must be described using Vehicle, flammable gas powered. This includes hybrid electric vehicles powered by both an internal combustion engine and wet, sodium or lithium batteries installed. a. Mixtures of one or more organic lead mixtures (such as tetraethyl lead, triethylmethyl lead, diethyldimethyl lead, ethyltrimethyl lead, and tetramethyl lead) with one or more halogen compounds (such as ethylene dibromide and ethylene dichloride), hydrocarbon solvents or other equally efficient stabilizers; or. N37 This material may be shipped in an integrally-lined fiber drum (1G) which meets the general packaging requirements of subpart B of part 173 of this subchapter, the requirements of part 178 of this subchapter at the packing group assigned for the material and to any other special provisions of column 7 of the 172.101 table. Packagings must be so constructed that explosion is not possible by reason of increased internal pressure. TP47 The 2.5 year internal examination may be waived or substituted by other test methods or inspection procedures specified by the competent authority or its authorized body, provided that the portable tank is dedicated to the transport of the organometallic substances to which this tank special provision is assigned. 142 These hazardous materials may not be classified and transported unless authorized by the Associate Administrator. B47 Each tank may have a reclosing pressure relief device having a start-to-discharge pressure setting of 310 kPa (45 psig). The shipper must ensure that all applicable requirements of 173.185 of this subchapter are met. is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. TP17 Only inorganic non-combustible materials may be used for thermal insulation of the tank. . Other inorganic nitrate salts may replace part of the ammonium nitrate. The HMT provides the basic information necessary to ship a hazardous material safely. 59 Ferrocerium, stabilized against corrosion, with a minimum iron content of 10 percent is not subject to the requirements of this subchapter. Stacking is permitted two or more levels high to achieve maximum allowable utilization of the designated vehicle, rail car weight, or intermodal freight container weight or vessel hold volume. (iv) T75. For example, nickel-metal hydride batteries transported by vessel in certain quantities are covered by another entry (see Batteries, nickel-metal hydride, UN3496). The outside of each package must be plainly marked ARTICLES, EXPLOSIVES, N.O.S. 74 During transport, this material must be protected from direct sunshine and stored or kept in a cool and well-ventilated place, away from all sources of heat. 21 This material must be stabilized by appropriate means (e.g., addition of chemical inhibitor, purging to remove oxygen) to prevent dangerous polymerization (see 173.21(f) of this subchapter). Cargo heaters must be reverse refrigeration (heat pump) units. W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings. N80 Packages consisting of one inner metal can, not over 2.5 kg (5.5 pounds) capacity, packed in an outer wooden or fiberboard box, or a wooden barrel, are authorized and need not conform to the requirements of part 178 of this subchapter. As a However this examination is required when the conditions of 180.605(f) are met. 22 If the hazardous material is in dispersion in organic liquid, the organic liquid must have a flash point above 50 C (122 F). Air must be eliminated from the vapor space by nitrogen or other means. Column 7 specifies codes for special provisions applicable to hazardous materials. Alternatively, the item itself may be used as a packaging if it meets the general packaging requirements of subparts A and B of part 173 of this subchapter. B52 Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. The articles may be transported as in Division 1.4 Compatibility Group D (1.4D) if all of the conditions specified in 173.63(a) of this subchapter are met. Large Packagings are authorized for the Packing Group III entries of specific proper shipping names when either special provision IB3 or IB8 is assigned to that entry in the 172.101 Table. A Shipper of a hazardous material is responsible for its classification and packaging prior to offering it for shipment to a Carrier. These detectors must have a minimum burst pressure of 1800 kPa as demonstrated by design type qualification testing; and. A112 Notwithstanding the quantity limits shown in Column (9A) and (9B) for this entry, the following IBCs are authorized for transportation aboard passenger and cargo-only aircraft. Formulations with low nitrocellulose contents and neither showing dangerous properties when tested for their ability to detonate, deflagrate or explode when heated under defined confinement by the appropriate test methods and criteria in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter), nor classed as a Division 4.1 (flammable solid) when tested in accordance with the procedures specified in 173.124 of this subchapter (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm), are not subject to the requirements of this subchapter.
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